What is a first-order reaction? Determine the integrated rate equation for a first-order reaction $R \to P$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) First-order reaction: $A$ reaction in which the rate of reaction is proportional to the first power of the concentration of the reactant $R$ is called a first-order reaction.
The rate of a first-order reaction $\propto [R]^1$.
For the reaction $R \to P$,the differential rate expression is:
$Rate = -\frac{d[R]}{dt} = k[R]$
$\therefore \frac{d[R]}{[R]} = -k dt \dots (i)$
Integrating this equation on both sides:
$\int \frac{d[R]}{[R]} = -\int k dt$
$\ln [R] = -kt + I \dots (ii)$
Here,$I$ is the constant of integration.
When $t = 0$,$[R] = [R]_0$,where $[R]_0$ is the initial concentration of the reactant. Substituting these values into equation $(ii)$:
$\ln [R]_0 = -k(0) + I \implies I = \ln [R]_0 \dots (iii)$
Substituting $I = \ln [R]_0$ into equation $(ii)$:
$\ln [R] = -kt + \ln [R]_0 \dots (iv)$
Rearranging the terms:
$kt = \ln [R]_0 - \ln [R]$
$kt = \ln \frac{[R]_0}{[R]}$
$k = \frac{1}{t} \ln \frac{[R]_0}{[R]} \dots (v)$
Converting to base $10$ logarithm:
$k = \frac{2.303}{t} \log \frac{[R]_0}{[R]} \dots (vi)$
Taking the antilog of equation $(iv)$,we get:
$[R] = [R]_0 e^{-kt} \dots (vii)$

Explore More

Similar Questions

Which of the following plots is(are) correct for the given reaction? $( [P]_0$ is the initial concentration of $P$ $)$

The integrated rate equation is $Rt = \log C_0 - \log C_t$. The straight line graph is obtained by plotting

Time required to decompose $SO_{2}Cl_{2}$ to half of its initial amount is $60 \ minutes$. If the decomposition is a first order reaction,calculate the rate constant of the reaction.

The unit of the specific reaction rate constant for a first-order reaction (if the concentration is expressed in molarity) is:

What is the value of the slope when a graph is plotted of $\log \frac{[R]_0}{[R]}$ versus $t$ (time) for a first-order reaction?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo